Temperature and Pressure Dependence of the Reaction S + CS (+M) → CS2 (+M)
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چکیده
منابع مشابه
Temperature and pressure dependence of ion-molecule association and dissociation reactions: the N2(+) + N2 (+ M) <--> N4+ (+ M) reaction.
Thermal dissociation and the reverse association reactions of molecular ions can be represented within the same framework as unimolecular reactions of neutral molecules. However, because of different intra- and intermolecular interaction potentials, some differences between ionic and neutral systems should also be expected. Starting from these generalities, the present article analyzes the temp...
متن کاملTemperature and Pressure Dependence of the Reaction
Experimental data for the unimolecular decomposition of CS2 from the literature are analyzed by unimolecular rate theory with the goal of obtaining rate constants for the reverse reaction S + CS (+M) → CS2 (+M) over wide temperature and pressure ranges. The results constitute an important input for the kinetic modeling of CS2 oxidation. CS2 dissociation proceeds as a spin-forbidden process whos...
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Subpicosecond time-resolved absorption measurements at 77 K on two reaction center (RC) mutants of Rhodobacter capsulatus are reported. In the D(LL) mutant the D helix of the M subunit has been substituted with the D helix from the L subunit, and in the D(LL)-FY(L)F(M) mutant, three additional mutations are incorporated that facilitate electron transfer to the M side of the RC. In both cases th...
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Root knot nematode is one of the important plant pathogens that causes damage to many crops, including greenhouse crops. Pepper is an agricultural crop which its cultivation has increased in recent years, especially in greenhouses. Most of the adopted management methods for this nematode have not met the required efficiency. In this study, reaction of some pepper cultivars (Elmina, Tuvana, Chal...
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ژورنال
عنوان ژورنال: The Journal of Physical Chemistry A
سال: 2015
ISSN: 1089-5639,1520-5215
DOI: 10.1021/jp5121492